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ChemInform Abstract: Enantioselective Total Synthesis of Gracilins B and C Using Catalytic Asymmetric Diels-Alder Methodology.

✍ Scribed by E. J. COREY; M. A. LETAVIC


Book ID
112027084
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Total Synthesis of
✍ S. YAO; M. JOHANNSEN; R. G. HAZELL; K. A. JOERGENSEN πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB

Total Synthesis of (R)-Dihydroactinidiolide and (R)-Actinidiolide Using Asymmetric Catalytic Hetero-Diels-Alder Methodology. -Key steps in the synthesis of title compounds (V) and (VI) are regio-and stereoselective hetero-Diels-Alder reaction of the diene (I) and subsequent rearrangement to the lac