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Total Synthesis of (±)-Maoecrystal V

✍ Scribed by Peng, Feng; Danishefsky, Samuel J.

Book ID
117988392
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
1015 KB
Volume
134
Category
Article
ISSN
0002-7863

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A diastereoselective route to the maoecrystal V core compound (6) has been achieved. Key transformations include an intramolecular Diels-Alder cyclization and an exo-glycal epoxide rearrangement sequence.