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Total Synthesis of (±) Maoecrystal V

✍ Scribed by Gong, Jianxian; Lin, Guang; Sun, Wenbo; Li, Chuang-Chuang; Yang, Zhen

Book ID
115313399
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
881 KB
Volume
132
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

Total Synthesis of (±)-Maoecrystal V
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✍ Peng, Feng; Danishefsky, Samuel J. 📂 Article 📅 2012 🏛 American Chemical Society 🌐 English ⚖ 1015 KB
Toward the total synthesis of maoecrysta
Toward the total synthesis of maoecrystal V: an intramolecular Diels–Alder route to the maoecrystal V pentacyclic core with the appropriate relative stereochemistry
✍ Feng Peng; Samuel J. Danishefsky 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 515 KB

A diastereoselective route to the maoecrystal V core compound (6) has been achieved. Key transformations include an intramolecular Diels-Alder cyclization and an exo-glycal epoxide rearrangement sequence.