Toward the Total Synthesis of Maoecrystal V: Establishment of Contiguous Quaternary Stereocenters
โ Scribed by Baitinger, Irina; Mayer, Peter; Trauner, Dirk
- Book ID
- 115533223
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 643 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1523-7060
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๐ SIMILAR VOLUMES
A diastereoselective route to the maoecrystal V core compound (6) has been achieved. Key transformations include an intramolecular Diels-Alder cyclization and an exo-glycal epoxide rearrangement sequence.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
An approach to the conjugated polyene chain component of orevactaene is reported. A modular approach has been devised to link the two stereocentre-containing ends of the structure together via a trisubstituted oleยฎn-template. Key to the success of this approach is an ecient `one pot' lithium/halogen