✦ LIBER ✦
Toward the total synthesis of maoecrystal V: an intramolecular Diels–Alder route to the maoecrystal V pentacyclic core with the appropriate relative stereochemistry
✍ Scribed by Feng Peng; Samuel J. Danishefsky
- Book ID
- 104098592
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- French
- Weight
- 515 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
A diastereoselective route to the maoecrystal V core compound (6) has been achieved. Key transformations include an intramolecular Diels-Alder cyclization and an exo-glycal epoxide rearrangement sequence.