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Total Synthesis of (+)-Dibromophakellin

✍ Scribed by Takuya Imaoka; Osamu Iwamoto; Kei-ichi Noguchi; Kazuo Nagasawa

Book ID: 101539438
Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 296 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200806233

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✍ Takuya Imaoka; Osamu Iwamoto; Kei-ichi Noguchi; Kazuo Nagasawa 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 296 KB

## Abstract **Two members of a family** of pyrrole–imidazole marine alkaloids, (+)‐dibromophakellin and the nonnatural congener (+)‐phakellin, were synthesized enantioselectively from 4‐hydroxy‐L‐proline. The chiral aminal at C10 was constructed efficiently by means of an Overman‐type [3,3] sigmatr

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