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Total Synthesis of the Natural Product (±)-Dibromophakellin and Analogues

✍ Scribed by Hewlett, Nicole M.; Tepe, Jetze J.

Book ID
125899914
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
42 KB
Volume
14
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES

Total Synthesis of (+)-Dibromophakellin
Total Synthesis of (+)-Dibromophakellin
✍ Takuya Imaoka; Osamu Iwamoto; Kei-ichi Noguchi; Kazuo Nagasawa 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 296 KB
Total Synthesis of (+)-Dibromophakellin
Total Synthesis of (+)-Dibromophakellin
✍ Takuya Imaoka; Osamu Iwamoto; Kei-ichi Noguchi; Kazuo Nagasawa 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 296 KB

## Abstract **Two members of a family** of pyrrole–imidazole marine alkaloids, (+)‐dibromophakellin and the nonnatural congener (+)‐phakellin, were synthesized enantioselectively from 4‐hydroxy‐L‐proline. The chiral aminal at C10 was constructed efficiently by means of an Overman‐type [3,3] sigmatr