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Thermolysis of dimethyl sulfoxide

✍ Scribed by F. C. Thyrion; G. Debecker

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
365 KB
Volume
5
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The thermal decomposition of dimethyl sulfoxide at small extent of reaction has been studied at temperatures of 297‐350Β°C and pressures of 10–400 Torr. The major products CH~4~, C~2~H~4~, and SO~2~ were shown to follow first‐order kinetics. The activation energies for production of each was about 48 kcalΒ·mole^βˆ’1^. A chain mechanism has been postulated in the light of the results of isotopic substitution experiments.

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