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Effects of substituents on the acid-catalyzed thermolysis of sucrose in dimethyl sulfoxide

✍ Scribed by Wayne Moody; Geoffrey N. Richards

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
455 KB
Volume
111
Category
Article
ISSN
0008-6215

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✦ Synopsis

The rates of acid-catalyzed degradation of a number of acetyl-substituted sucrose derivatives in dimethyl sulfoxide have been determined. The results indicate that the rate is markedly diminished by acetylation at O-l or -3 of the D-fructosyl group. This increased stability of the substituted sucrose derivatives is also reflected in an increased stability of the D-fructose derivatives that are formed in the reaction.

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