Desulfuration of Thio-Acids with Dimethyl Sulfoxide
✍ Scribed by Dr. M. Mikołajczyk
- Publisher
- John Wiley and Sons
- Year
- 1966
- Tongue
- English
- Weight
- 103 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Chlorinated cis-2,4-pentadienoyl chlorides (1) with R = H or CsHs and R' = CI react in the same way but more slowly (reaction time: 4 days). Ci2H2s C14Hz9 Ci6H13 Ci8H37 Benzyl Cyclohexyl Phenyl
Monothioacetic acid is also desulfurated by dimethyl sulfoxide; the yield is 70% after one week at 2OoC.
📜 SIMILAR VOLUMES
## Abstract **Summary:** Carboxylic acids were efficiently activated with __N__,__N′__‐carbonyldiimidazole (CDI) and applied for the acylation of cellulose under homogeneous conditions using dimethyl sulfoxide (DMSO)/tetrabutylammonium fluoride trihydrate (TBAF) as solvent. The simple and elegant m