Mechanism of dimethyl sulfoxide-induced hemolysis
β Scribed by William P. Norred; Howard C. Ansel; Ivan L. Roth; James J. Peifer
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 671 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0022-3549
No coin nor oath required. For personal study only.
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## Abstract The reactions of methyl and methylperoxyl radicals derived from dimethyl sulfoxide (DMSO) with hydrogen peroxide, peroxymonocarbonate (HCO~4~^β^), and persulfate were studied. The major reaction observed for the hydroperoxides was the abstraction of the hydrogen atom by the radicals. Th
## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramineβT (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is β__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t