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Carbocation-Forming Reactions in Dimethyl Sulfoxide.

✍ Scribed by Xavier Creary; Elizabeth A. Burtch; Ziqi Jiang

Publisher
John Wiley and Sons
Year
2003
Weight
54 KB
Volume
34
Category
Article
ISSN
0931-7597

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The reactions of p-O 2 NC 6 H 4 CH 2 Cl with (RO) 2 PO β€«Χžβ€¬ in Me 2 SO with R ‫ב‬ Me, Et, Pr, Bu, CF 3 CH 2 , i-Pr or Ph involve the formation of p-O 2 NC 6 H 4 CH 2 P(O)(OR) 2 by S N 2 substitution followed by a further S RN 1 p-nitrobenzylation of p-O 2 NC 6 H 4 CH[P(O)(OR) 2 ] β€«Χžβ€¬ and p-O 2 NC 6 H