𝔖 Bobbio Scriptorium
✦   LIBER   ✦

“Carbocation Watching” in Solvolysis Reactions

✍ Scribed by Heike F. Schaller; Herbert Mayr


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
312 KB
Volume
47
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Mechanisms of elimination and substituti
✍ Qingshui Meng; Baoan Du; Alf Thibblin 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 78 KB

The reactions of 4-(4'-nitrophenyl)-4-X-butan-2-one (1-X; X = Cl, OTs) with added bases/nucleophiles exhibit second-order kinetics. These substitution and elimination reactions are concluded to be of concerted S N 2 type and irreversible E1cB type, respectively. The spontaneous formation of alkene f