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Chemical Reactions of Dimethyl Sulfoxide in a Plasma Discharge

✍ Scribed by Dr. Klaus Gorzny; Dr. Günther Maahs

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
229 KB
Volume
12
Category
Article
ISSN
0044-8249

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The reactions of p-O 2 NC 6 H 4 CH 2 Cl with (RO) 2 PO ‫מ‬ in Me 2 SO with R ‫ס‬ Me, Et, Pr, Bu, CF 3 CH 2 , i-Pr or Ph involve the formation of p-O 2 NC 6 H 4 CH 2 P(O)(OR) 2 by S N 2 substitution followed by a further S RN 1 p-nitrobenzylation of p-O 2 NC 6 H 4 CH[P(O)(OR) 2 ] ‫מ‬ and p-O 2 NC 6 H