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The thermolysis and photochemistry of hybrid initiators for ‘living’ free radical polymerization

✍ Scribed by W.G. Skene; Terrence J. Connolly; J.C. Scaiano

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
317 KB
Volume
40
Category
Article
ISSN
0040-4039

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Trapping of photogenerated group IV radi
Trapping of photogenerated group IV radicals by TEMPO: Potential new organometallic initiators for “living” free radical polymerization
✍ W. G. Skene; Terrence J. Connolly; J. C. Scaiano 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 103 KB 👁 1 views

A series of trialkyl and triaryl organometallic radicals from group IV generated by hydrogen abstraction by tert-butoxyl radical from the parent hydrides have been examined using laser flash photolysis. The rate constants for the trapping of the metal-centered radicals by the persistent radical TEMP