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Studies on the initiation of a free-radical condensation hybrid polymerization system

✍ Scribed by Xiaoyin Hong; Qidao Chen; Ming Chen; Rongzhen Yu; Jing Chen

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 128 KB
Volume: 79
Category: Article
ISSN: 0021-8995
DOI: 10.1002/1097-4628(20010214)79:7<1195::aid-app60>3.0.co;2-i

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## Abstract The polymerization kinetics of acrylonitrile (AN) with the potassium persulfate (K~2~S~2~O~8~)/thiourea redox system has been investigated volumetrically in an aqueous medium in the temperature range of 40–80°C. The rate of polymerization (__R__~__p__~) and rate of K~2~S~2~O~8~ disappea