Sulfonyl chlorides as initiators for the ruthenium-mediated living radical polymerization of methyl methacrylate
โ Scribed by Mutsuhiro Matsuyama; Masami Kamigaito; Mitsuo Sawamoto
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 368 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0887-624X
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๐ SIMILAR VOLUMES
## Abstract The reverse atom transfer radical polymerization (RATRP) technique using CuCl~2~/bipyridine (bipy) complex as a catalyst was applied to the living radical polymerization of methyl methacrylate (MMA). A hexaโsubstituted ethane thermal iniferter, diethyl 2,3โdicyanoโ2,3โdiphenylsuccinate
## Abstract Three novel iniferter reagents were synthesized and used as initiators for the polymerizations of methyl methacrylate (MMA) and styrene (St) in the presence of copper(I) bromide and __N,N,N__โฒ,__N__โณ,__N__โณโpentamethyldiethylenetriamine at 90 and 115ยฐC, respectively. All the polymerizat
## Abstract The bimetallic ruthenium complex [(1,3,5โ__i__โPr~3~C~6~H~3~)Ru(ฮผโCl)~3~RuCl(C~2~H~4~)(PCy~3~)] has been synthesized by reaction of [(1,3,5โ__i__โPr~3~C~6~H~3~)RuCl~2~)]~2~ with one equivalent of PCy~3~ in the presence of ethylene. It can be used as a catalyst precursor for the controll