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Synthesis of new free-radical initiators for polymerization

✍ Scribed by B. Gawdzik; J. Ksiȩżopolski; T. Matynia

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
56 KB
Volume
87
Category
Article
ISSN
0021-8995

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📜 SIMILAR VOLUMES

New peracid-type polymeric initiator for
New peracid-type polymeric initiator for radical polymerization
✍ Ging-Ho Hsiue; Tirng-Lair Perng; Jen-Ming Yang 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB

In this study, a radiation-induced copolymer, namely polyethylene-g-acrylic acid powder, was used, whose carboxyl groups can be oxidized to form a highly reactive polymer initiator. The activation energy for its decomposition is 22.4 kcal/mol. It was found that the peracidtype polymeric powder was e