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Photochemical synthesis of TEMPO-capped initiators for “living” free radical polymerization

✍ Scribed by Terrence J. Connolly; M.V. Baldoví; N. Mohtat; J.C. Scaiano

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
309 KB
Volume
37
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

Trapping of photogenerated group IV radi
Trapping of photogenerated group IV radicals by TEMPO: Potential new organometallic initiators for “living” free radical polymerization
✍ W. G. Skene; Terrence J. Connolly; J. C. Scaiano 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 103 KB 👁 1 views

A series of trialkyl and triaryl organometallic radicals from group IV generated by hydrogen abstraction by tert-butoxyl radical from the parent hydrides have been examined using laser flash photolysis. The rate constants for the trapping of the metal-centered radicals by the persistent radical TEMP