A series of initiators have been developed for living radical polymerization of methyl methacrylate (MMA) mediated by ruthenium(If) complexes [e.g., RuCI2(PPh3)3; Ph = C6H5]. These initiators include chloromethanes, ~-chloroesters, ct-chloroketones, and cc-bromoesters, among which CCI3COCH3, CHCI2CO
✦ LIBER ✦
Designing functional aromatic multisulfonyl chloride initiators for complex organic synthesis by living radical polymerization
✍ Scribed by Virgil Percec; Bogdan Barboiu; Tushar K. Bera; Marcel Van Der Sluis; Robert B. Grubbs; Jean M. J. Fréchet
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 501 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
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