The thermal rearrangement of endo-7-methyl-exo-7-vinylbicyclo[3.2.0]Hept-2-ene
β Scribed by Mark A. Forman; Phyllis A. Leber
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 224 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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Derivatives of trans-bicyclo[4.1.0]hept-3-ene with chlorine and bromine substituents the 7 position were synthesized and their thermal rearrangements were examined. Thermolysis of the dichloride leads to the formation of the cis-fused isomer, while heating the dibromide results in ring-expanded prod