The thermal rearrangement of 6-methyl-6-vinylbicyclo)[3.2.0]heptane
✍ Scribed by Timothy E Glass; Phyllis A Leber
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 272 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
oo4o-4(n9190 53.00 + .tM FIiW!diIlGnuBriuin p~'8amoo Press pk ' This is presumably an indirect diical-mediated [l.!i]-hydrogen shit product; its GC retention time is slightly different from that observed for qimer A. the close proximity of the C-4 e&o-hydrogen to the migration terminus.8 Chickos and Frey have previously concluded that an analogous [ lJ]-hydrogen shit in 2.2~dimethyl-1-vinylcyclobutane is concerted.~ However,
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## Abstract Acid‐catalyzed rearrangement of 6‐phenylbicyclo[3.2.0]heptan‐6‐ol gave 1,1′‐biphenyl and 1,1′‐biphenyl‐carbaldehydes in small amounts as well as the expected rearrangement products. A detailed study of the reaction mechanism revealed that the conversion occurs __via__ an oxidative proce