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The thermal rearrangement of 6-methyl-6-vinylbicyclo)[3.2.0]heptane

✍ Scribed by Timothy E Glass; Phyllis A Leber


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
272 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis


oo4o-4(n9190 53.00 + .tM FIiW!diIlGnuBriuin p~'8amoo Press pk ' This is presumably an indirect diical-mediated [l.!i]-hydrogen shit product; its GC retention time is slightly different from that observed for qimer A. the close proximity of the C-4 e&o-hydrogen to the migration terminus.8 Chickos and Frey have previously concluded that an analogous [ lJ]-hydrogen shit in 2.2~dimethyl-1-vinylcyclobutane is concerted.~ However,


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An Oxidative Rearrangement of 6-Phenylbi
✍ Mustafa Ceylan; Esra Fındık; Hasan Seçen 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 German ⚖ 203 KB

## Abstract Acid‐catalyzed rearrangement of 6‐phenylbicyclo[3.2.0]heptan‐6‐ol gave 1,1′‐biphenyl and 1,1′‐biphenyl‐carbaldehydes in small amounts as well as the expected rearrangement products. A detailed study of the reaction mechanism revealed that the conversion occurs __via__ an oxidative proce