Novel Rearrangement of a Bicyclo[3.2.0]heptan-6-one to a Bicyclo[3.2.0]heptan-2-one
โ Scribed by Z. Grudzinski; S.M. Roberts
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 147 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The known 6,6โdimethoxy bicyclo [3.2.0]heptanโ2โone, obtained by (~ฯ~ 2 + ~ฯ~ 2) photocycloaddition of 2โcyclopentenone and 1, 1โdimethoxyethene, is an adequate precursor for prostanoid synthons. Its conversion into intermediates for the 11โdesoxyprostaglandin (PG) series and for PGC~2~
Na, NH3(1) C2H50H \ (\_ Cl CN Cl CN The efficient synthesis of bicyclot2.2.Olhexenes from cyclobutadieneiron tricarbonyl provides a ready source variety of small ring compounds, efforts in the near future. of starting materials for the preparation of a and we hope to describe other, related syntheti