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6,6-Dimethoxy Bicyclo[3.2.0]Heptan-2-One: An Intermediate for Prostanoid Synthons

✍ Scribed by Denis De Keukeleire; Hugo de Wilde; Frank Verzele; Wilfried Wyffels; Maurits Vandewalle

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
372 KB
Volume
88
Category
Article
ISSN
0037-9646

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✦ Synopsis

Abstract

The known 6,6‐dimethoxy bicyclo [3.2.0]heptan‐2‐one, obtained by (~π~ 2 + ~π~ 2) photocycloaddition of 2‐cyclopentenone and 1, 1‐dimethoxyethene, is an adequate precursor for prostanoid synthons. Its conversion into intermediates for the 11‐desoxyprostaglandin (PG) series and for PGC~2~ is described.

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