ChemInform Abstract: The Bicyclo[3.2.0]heptan-endo-2-ol and Bicyclo[3.2.0]hept-3-en-6-one Approaches in the Synthesis of Grandisol: The Evolution of an Idea and Efforts to Improve Versatility and Practicality
β Scribed by Emanuela Marotta; Paolo Righi; Goffredo Rosini
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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An Alternative Diastereospecific Approach to (Β±)-Samin and 2,6-Diaryl-3,7-dioxabicyclo[3.3.0]octane [Furanofuran] Lignans Based on the Ireland-Claisen Rearrangement of Unsaturated Oxa-macrolides. -Ireland-Claisen rearrangement of the macrolide (II) gives stereospecifically the tetrahydrofurancarbox