Tricyclo[3.1.1.03,6]Heptanes: Synthesis from a bicyclo[2.2.0]hexane
β Scribed by J. Meinwald; J. Mioduski; Spencer T. Olin
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 165 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Na, NH3(1) C2H50H \ (_ Cl CN Cl CN The efficient synthesis of bicyclot2.2.Olhexenes from cyclobutadieneiron tricarbonyl provides a ready source variety of small ring compounds, efforts in the near future. of starting materials for the preparation of a and we hope to describe other, related synthetic
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The triplet sensitized irradiation of 3-allyl-diaryl-substituted cyclopropenes to m.l.O]hex-2-enes proceeds via an intramolecular [2+2]-cycloaddition followed by a subsequent rearrangement of the initially formed tricycl0[2.2.0.0~~~]hexane skeleton. Previous work from this laboratory has shown that