The thermal rearrangement of 7-ethyl-7-methylbicyclo[3.2.0]hept-2-ene (1)
✍ Scribed by Timothy E. Glass; David M. Goldstein; Phyllis A. Leber
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 233 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond
## Abstract The gas‐phase thermal decomposition of 7,7‐dimethylbicyclo[3.2.0]hept‐2‐en‐6‐one (DBH) to yield cyclopentadiene and 1,1‐dimethylketene as primary products was studied in the temperature range of 470‐550 °K using a static reaction system. First‐order rate constants for the depletion of D