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Regio- and stereoselective electrophilic additions to exo and endo-2-hydroxy-2-methyl-7-oxabicyclo[2.2.1]hept-5-ene

✍ Scribed by Odón Arjona; Roberto Fernandez de la Pradilla; Rosa A. Pérez; Joaquín Plumet; Alma Viso


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
139 KB
Volume
28
Category
Article
ISSN
0040-4039

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Regioselective Radical Additions to 7-Ox
✍ Jean-Paul Vionnet; Kurt Schenk; Philippe Renaud 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 658 KB

## Abstract Radical addition to 7‐oxabicylco[2.2.1]hept‐5‐en‐2‐one (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the