Regioselective Radical Additions to 7-Ox
✍
Jean-Paul Vionnet; Kurt Schenk; Philippe Renaud
📂
Article
📅
1993
🏛
John Wiley and Sons
🌐
German
⚖ 658 KB
## Abstract Radical addition to 7‐oxabicylco[2.2.1]hept‐5‐en‐2‐one (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the