Chemo- and stereoselective functionalization of 7-oxabicyclo[2.2.1]hept-5-en-2-one with dichloroketene
✍ Scribed by Odón Arjona; Roberto Fernández de la Pradilla; Sonia Pérez; Joaquín Plumet; Pierre-Alain Carrupt; Pierre Vogel
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 140 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Radical addition to 7‐oxabicylco[2.2.1]hept‐5‐en‐2‐one (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the
Dedicated to Prof. Ch. Tamm on the occasion of his 60th birthday (12.4.83) ## Summary (-)-1-Camphanoyloxyacrylonitrile (= (-)-1 -cyanovinyl camphanate; 1) obtained from the commercially available ( -)-camphanoyl chloride and 2-0x0propiononitrile added to furan at 20" in the presence of CU(BF,)~.