## Abstract Radical addition to 7‐oxabicylco[2.2.1]hept‐5‐en‐2‐one (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the
✦ LIBER ✦
Synthesis of (±)-isoavenaciolide and of (±)-ethisolide from (±)-7-oxabicyclo[2.2.1]hept-5-en-2-one.
✍ Scribed by Janine Cossy; Jean-Luc Ranaivosata; Véronique Bellosta
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 567 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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