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The thermal deazetation of 6,6,7,7-tetrafluoro-2,3-diazabicyclo[3.2.0]hept-2-ene

โœ Scribed by William R. Dolbier Jr.; Dheya M. Al-Fekri


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
209 KB
Volume
24
Category
Article
ISSN
0040-4039

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Thermal deasetation of difluoro-and tetrafluoro-2,3-diasabicyclo[3.2.0lhept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloadd~on process. A key finding was the absence of isolation of

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