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Reduction of bicyclo[3.2.0] hept-2-en-6-one and 7,7-dimethylbicyclo[3.2.0]hept-2-en-6-one using dehydrogenase enzymes and the fungus mortierella ramanniana

✍ Scribed by Suzanne Butt; H.Geoff Davies; Michael J. Dawson; Gordon C. Lawrence; Jeff Leaver; Stanley M. Roberts; Michael K. Turner; Basil J. Wakefield; Wilfred F. Wall; John A. Winders

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
233 KB
Volume
26
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

The gas-phase thermal unimolecular elimi
The gas-phase thermal unimolecular elimination of 1,1-dimethylketene from 7,7-dimethylbicyclo[3.2.0]hept-2-en-6-one
✍ Kurt W. Egger πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 476 KB

## Abstract The gas‐phase thermal decomposition of 7,7‐dimethylbicyclo[3.2.0]hept‐2‐en‐6‐one (DBH) to yield cyclopentadiene and 1,1‐dimethylketene as primary products was studied in the temperature range of 470‐550 Β°K using a static reaction system. First‐order rate constants for the depletion of D

Pure enantiomers of bicyclo[3.2.0]hept-3
Pure enantiomers of bicyclo[3.2.0]hept-3-en-6-ones and bicyclo[3.2.0]hept-3-en-6-endo-ols: Resolution, absolute configuration and optical properties
✍ Emanuela Marotta; Ilaria Pagani; Paolo Righi; Goffredo Rosini; Valerio Bertolasi πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 596 KB

Single crystal X-ray diffraction analysis of compounds A, B and, C helped us to assign the absolute configurations of the enantiomers of the bicyclo[3.2.0]hept-3-en-6-endo-ols 4-6. These bicyclic alcohols were easily obtained by: (i) stereoselective reductions of the bicyclo[3.2.0]hept-3-en-6-ones 1

Reduction of 7-chlorobicyclo[3.2.0]hept-
Reduction of 7-chlorobicyclo[3.2.0]hept-2-en-6-ones catalysed by 3Ξ±, 20Ξ²-hydroxysteroiddehydrogenase
✍ H. Geoff Davies; Thomas C.C. Gartenmann; Jeff Leaver; Stanley M. Roberts; Michae πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 110 KB

The enzymes are stirred together with Eupergit-C (Dumas Chemicals) in 1M phosphate buffer (pH 7.5) over 96 h at 4OC. 10. 7endo-Chloro-7exo-methylbicyclo[3.2.0]hept-2~en-6-one was reduced by HSDH to give optically pure-&do-alcohol.