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Reduction of 7-chlorobicyclo[3.2.0]hept-2-en-6-ones catalysed by 3α, 20β-hydroxysteroiddehydrogenase

✍ Scribed by H. Geoff Davies; Thomas C.C. Gartenmann; Jeff Leaver; Stanley M. Roberts; Michael K. Turner

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 110 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(86)80057-0

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✦ Synopsis

The enzymes are stirred together with Eupergit-C (Dumas Chemicals) in 1M phosphate buffer (pH 7.5) over 96 h at 4OC. 10. 7endo-Chloro-7exo-methylbicyclo[3.2.0]hept-2~en-6-one was reduced by HSDH to give optically pure-&do-alcohol.

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