Steric effects in the dehydrohalogenation of 7-halo-bicyclo [3.2.0] hept-2-en-6-ols
✍ Scribed by Rima Huston; Max Rey; Andre S. Dreiding
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 442 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0037-9646
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract The proton spectra of bicyclo[3.2.0]hept‐2‐en‐6‐one and the 7,7‐dimethyl, 7,7‐dichloro and 7‐__endo__‐chloro derivatives were analysed and the chemical shifts and coupling constants are reported. Molecular modelling and chemical shift calculations together with the observed couplings sh
## Abstract The gas‐phase thermal decomposition of 7,7‐dimethylbicyclo[3.2.0]hept‐2‐en‐6‐one (DBH) to yield cyclopentadiene and 1,1‐dimethylketene as primary products was studied in the temperature range of 470‐550 °K using a static reaction system. First‐order rate constants for the depletion of D
## Abstract Bicyclo[3.2.0]hept‐6‐ene was converted into the corresponding addition polymer poly(6,7‐bicyclo[3.2.0]heptylene) with the aid of early and late transition metal based olefin polymerisation catalysts. Moderate to very good yields (42–99%) of polymer were obtained with [Pd(NCEt)~4~][BF~4~