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The stereochemical dependence of the vicinal 13C14N coupling constant as a constitutional probe

✍ Scribed by Ludo A. Valckx; Frans A. M. Borremans; Chris E. Becu; Robert H. K. De Mar; Marc. J. O. Anteunis

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
389 KB
Volume
12
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The magnitudes of ^13^C^14^N coupling constants have been measured in 12 rigid or anancomeric (biased) tetraalkylammonium iodides. The one‐bond coupling is typical for the degree of substitution of the carbon atom and the geminal coupling is very small. Vicinal couplings depend on the dihedral angle and other factors.

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