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13C NMR: Stereochemical dependence of the one-bond coupling constant 1J13CH in α-halogenoketones

✍ Scribed by J. Cantacuzene; R. Jantzen; M. Tordeux; C. Chachaty

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
135 KB
Volume
7
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The one‐bond coupling constant ^1^J ^13^CH for the halogenated carbon in α‐halogenocyclohexanones is more important when the CH bond is in the equatorial then in the axial position. When a conformational equilibrium is present, the resulting coupling is a linear function of the equilibrium constant.

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