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Dependence of one-bond deuterium isotope shifts in 13C NMR on CH bond lengths for substituted and unsubstituted aromatic compounds

✍ Scribed by Yasuki Nakashima; Takashi Teranishi; Toshiya Suzuki; Tyo Sone; Kensuke Takahashi

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
319 KB
Volume
32
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

One‐bond deuterium‐induced isotope shifts of ^13^C NMR (^1^Δ) for 106 sp^2^‐hybridized carbons are discussed in terms of CH bond lengths. ^1^Δ correlates linearly with the related CH bond length calculated by the MNDO MO method by the equation ^1^Δ(ppb)=8350 r~CH~ (Å) – 8824.

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