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Studies of 13CH coupling constants: III—the conformational dependence of 1J(13CH) for the formyl proton in aromatic aldehydes

✍ Scribed by D. F. Ewing

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
282 KB
Volume
6
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^1^J(^13^CH) and ^2^J(^13^CH) involving the aldehydic proton in ortho‐alkylbenzaldehydes have been examined for evidence of a hyperconjugative contribution from the aromatic π‐electrons. The expected hyperconjugative effect is obscured by changes in the coupling constants resulting from steric inhibition of resonance.

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