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The 13C,H coupling constants in structural and conformational analysis: II The correlation of 3J(HCCH) and 3J(CH3CCH) in ethylenes and their methyl derivatives

✍ Scribed by Pertti Äyräs

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
182 KB
Volume
9
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The vicinal ^3^J(CH~3~CCH) coupling constants were determined for a number of propylene derivatives and compared with the ^3^J(HCCH) couplings of the corresponding ethylenes. A linear regression analysis yielded the correlation ^3^J(CH) = 0.46 ×^3^ J(HH)+1.58 Hz, the correlation coefficient being 0.956.

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