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The conformational dependence of vicinal 13C13C spin–spin coupling constants in alicyclic compounds

✍ Scribed by Stefan Berger

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
324 KB
Volume
14
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

A series of alicyclic compounds with dihedral angles of 0°, 60°, 90°, 120° and 180° between a ^13^C‐labelled carbon atom and a carbon atom separated by three bonds from the label has been synthesized. The vicinal ^13^C^13^C spin coupling constants were measured, and from the results a Karplus‐type relationship between ^13^C^13^C spin coupling and dihedral angle is proposed.

📜 SIMILAR VOLUMES

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