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13C13C spin coupling constants in phenanthrene derivatives

✍ Scribed by Stefan Berger; Klaus Peter Zeller

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
469 KB
Volume
11
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The synthesis of six 1‐X‐ (X = OH, OCH~3~, OCOCH~3~, CH~3~, CHO and CN) phenanthrene derivatives with a ^13^C label at C‐1 is described. An analysis of the ^13^C^13^C spin coupling constants shows the importance of π‐interaction for the coupling constant transmission. Small ^13^C^13^C spin coupling constants over 6 bonds are reported.

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