The rotational spectrum of the ground state, the excited \(A\) states \(\nu_{3}, 2 \nu_{3}\) and probably \(\nu_{2}\), and the lowest \(E\) state \(v_{6}\) of \(\mathrm{CH}^{35} \mathrm{Cl}_{3}\) have been measured. The ground state microwave spectrum was analyzed to obtain nuclear quadrupole coupli
The Rotational Spectrum of OH in the v = 0-3 Levels of Its Ground State
โ Scribed by T.D. Varberg; K.M. Evenson
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 641 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0022-2852
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โฆ Synopsis
Rotational and fine structure transitions have been observed between low rotational levels in the (v=0-3) levels of the (\mathrm{OH} X^{2} \Pi) state by tunable far-infrared spectroscopy. The rotational and fine structure constants of the ground state have been refined by least-squares fitting to the observed data in combination with far-infrared and microwave measurements by other authors. Pressureinduced frequency shifts with helium as a buffer gas are also reported for some of the (v=0) transitions. ci 1993 Academic Press, Inc.
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The ground state rotational spectrum of \(\mathrm{CHF}_{2} \mathrm{Cl}\) has been observed and analyzed in the frequency region \(70-1280 \mathrm{GHz}\). Transitions with values of \(J\) up to 80 have been observed and the centrifugal distortion analysis of the spectrum has been performed using both