✦ LIBER ✦

Rotational Spectrum of the AsH2 Radical in Its Ground State, Studied by Far-Infrared Laser Magnetic Resonance

✍ Scribed by Rebecca A. Hughes; John M. Brown; Kenneth M. Evenson

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 402 KB
Volume: 200
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1999.8037

No coin nor oath required. For personal study only.

✦ Synopsis

The rotational spectrum of AsH 2 in its ground X ˜2B 1 electronic state has been recorded using a far-infrared laser magnetic resonance spectrometer. The AsH 2 radical was produced inside the spectrometer cavity by the reaction of arsine (AsH 3 ) with fluorine atoms. Hyperfine splittings from both 75 As and 1 H nuclei were observed, and analysis of the spectra has yielded accurate values for rotational, hyperfine, and Zeeman parameters.

📜 SIMILAR VOLUMES

Rotational Spectrum of the AsH Radical i

Rotational Spectrum of the AsH Radical in Itsa1Δ State, Studied by Far-Infrared Laser Magnetic Resonance

✍ Rebecca A. Hughes; John M. Brown; Kenneth M. Evenson 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 192 KB

The rotational spectrum of AsH in its metastable a 1 D state has been recorded using a far-infrared laser magnetic resonance spectrometer. The AsH radical was produced inside the spectrometer by the reaction of arsine (AsH 3 ) with fluorine atoms. Hyperfine splittings from both 75 As and 1 H nuclei

The Diode Laser Infrared Spectrum of the

The Diode Laser Infrared Spectrum of the Arsenic Monoxide Radical in Its Ground Electronic State (2Π)

✍ K. Essig; H. Jones; F. Ito; H. Takeo 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 243 KB

The infrared spectrum of the AsO radical in its \({ }^{2} \mathrm{Il}\) ground state has been measured using a diode laser spectrometer. Rovibrational transitions of the fundamental and a number of hot bands were measured in both \({ }^{2} \Pi_{3 / 2}\) and the \({ }^{2} I_{1 / 2}\) substates to an

Ground State Rotational Spectrum of CHF2

Ground State Rotational Spectrum of CHF2Cl in the Millimeter-Wave and Far-Infrared Region

✍ G. Cazzoli; G. Cotti; C.D. Esposti 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 470 KB

The ground state rotational spectrum of \(\mathrm{CHF}_{2} \mathrm{Cl}\) has been observed and analyzed in the frequency region \(70-1280 \mathrm{GHz}\). Transitions with values of \(J\) up to 80 have been observed and the centrifugal distortion analysis of the spectrum has been performed using both

Far-Infrared Laser Magnetic Resonance Sp

Far-Infrared Laser Magnetic Resonance Spectroscopic Study of the ν2 Bending Fundamental of the CCN Radical in Its X̃2Πr State

✍ Michael D. Allen; Kenneth M. Evenson; David A. Gillett; John M. Brown 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 279 KB

Bending vibration-rotation transitions between the (010) 2 ⌺ Ϫ and (000) 2 ⌸ r vibronic states of the CCN radical in its ground electronic state have been observed using far-infrared laser magnetic resonance (FIR LMR) spectroscopy. Thirteen FIR laser lines were used to record 769 resonances. The LMR