The rotational spectrum of AsH 2 in its ground X ˜2B 1 electronic state has been recorded using a far-infrared laser magnetic resonance spectrometer. The AsH 2 radical was produced inside the spectrometer cavity by the reaction of arsine (AsH 3 ) with fluorine atoms. Hyperfine splittings from both 7
Rotational Spectrum of the AsH Radical in Itsa1Δ State, Studied by Far-Infrared Laser Magnetic Resonance
✍ Scribed by Rebecca A. Hughes; John M. Brown; Kenneth M. Evenson
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 192 KB
- Volume
- 184
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The rotational spectrum of AsH in its metastable a 1 D state has been recorded using a far-infrared laser magnetic resonance spectrometer. The AsH radical was produced inside the spectrometer by the reaction of arsine (AsH 3 ) with fluorine atoms. Hyperfine splittings from both 75 As and 1 H nuclei were observed, and analysis of the spectra yielded accurate values for rotational, hyperfine, and Zeeman parameters.
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