The role of the rotational state in intermolecular interactions of H2O with H2and CH3Cl
β Scribed by E. J. van Duijn; L. J. F. Hermans
- Book ID
- 110561648
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 303 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0195-928X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The ability to use calculated OH frequencies to assign experimentally observed peaks in hydrogen bonded systems hinges on the accuracy of the calculation. Here we test the ability of several commonly employed model chemistriesβHF, MP2, and several density functionals paired with the 6β3
## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215β340 nm. By scaling to Ο(CH~3~O~2~)~240 nm~ = (4.24 Β± 0.27) Γ 10^β18^, the following absorption cross sections were determined: Ο(HO~2~)~240 nm~ = 1.29 Β± 0
The presence cf two sets of inequivalent trimeric clusters in [CI~O(CH~COO)~(H~O:~~ C1.6H20 at low tempera ture has been confirrrk-l by luminescence and luminescence excitation spectroscopy. Assignments of the four lowest levels of the lowest electr~.+cally excited state have been made. The ground