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The kinetics and mechanism of the reaction of H2O2 with K[RuIII(PDTA-H)Cl]·2H2O and K[RuIII(HEDTA-H)Cl]

✍ Scribed by M.M.Taqui Khan; R.M. Naik

Publisher: Elsevier Science
Year: 1989
Weight: 467 KB
Volume: 54
Category: Article
ISSN: 0304-5102
DOI: 10.1016/0304-5102(89)80210-x

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The reactions of C1 and Br atoms with HzOz have been studied in the range of 300-350 K using the very-low-pressure-reactor technique. It was found that metathesis to produce HX and H02 is the only significant process (199%). For the reaction of Br 2 Br + HzO2 + HBr + HOz k z (300 K) = 1.3 f 0.45 X a