Interaction of methanesulfonic acid with actinide ions. The new complexes HImid[Np(C2O4)(CH3SO3)3(H2O)2], [NpO2(Terpy)(CH3SO3)(H2O)]·2H2O, and [UO2(CH3SO3)2(H2O)]
✍ Scribed by G. B. Andreev; N. A. Budantseva; I. G. Tananaev; B. F. Myasoedov
- Book ID
- 111455869
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 223 KB
- Volume
- 51
- Category
- Article
- ISSN
- 1066-3622
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📜 SIMILAR VOLUMES
## Abstract The title compounds are the first examples of solvent‐free oxide methanesulfonates of Mo, U, Re, and V.
Methylperoxy radicals were generated by the flash photolysis of azomethane-oxygen mixtures. The observed broadband spectrum of the CH302 radical is similar, but not identical to those reported previously. The CH:302 decay followed second-order kinetics a t high CH:jOz concentrations with k4, = (2.5
Beibehaltung von Tetraederbaueinheiten [M0,l6aus Elektroneutralitatsgrunden zusatzlich zu einem MO ein M,O eingebaut werden. Bei MO :M,O = 1 sollten dann neben lose gebundenen Alkalien nur Netzwerkbildner vorliegen. Eine weitere Erhohung des MO-Gehaltes iiber diesen Alkalibetrag hinaus. bewirkt den
The mechanism of H$O4 formation via the reaction steps, SO1 t O$SO "\*' 3-(SO,: H,O) +H,SO,, has been investigated at low temperature in an argon matrix. Photooxydation of SO2 mainly occurs through the SO\*: O3 pairs. Photolysis of a SOI-H20-0, mixture did not lead to the H,SO, molecule. The I : 1 H