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The Reaction of Unsaturated Aliphatic Oxygenates with Ozone

✍ Scribed by Eric Grosjean; Daniel Grosjean

Book ID: 110232301
Publisher: Springer Netherlands
Year: 1999
Tongue: English
Weight: 122 KB
Volume: 32
Category: Article
ISSN: 0167-7764
DOI: 10.1023/a:1006122000643

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📜 SIMILAR VOLUMES

Rate constants for the gas-phase reactio

Rate constants for the gas-phase reaction of ozone with unsaturated oxygenates

✍ Eric Grosjean; Daniel Grosjean 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB 👁 2 views

The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ϭ 1 constants, in units of cm 3 molecule Ϫ1 s Ϫ1 , are for 2 (5H)-furanone, Ϫ18 10 0.22 Ϯ 0.05 for methacrolein, for crotonaldehyde, f

The Gas Phase Reaction of Unsaturated Ox

The Gas Phase Reaction of Unsaturated Oxygenates with Ozone: Carbonyl Products and Comparison with the Alkene-Ozone Reaction

✍ Eric Grosjean; Daniel Grosjean 📂 Article 📅 1997 🏛 Springer Netherlands 🌐 English ⚖ 106 KB

Rate constants for the gas-phase reactio

Rate constants for the gas-phase reactions of Ozone with unsaturated Aliphatic Alcohols

✍ Eric Grosjean; Daniel Grosjean 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 431 KB 👁 1 views

The gas-phase reaction of ozone with unsaturated alcohols in air has been investigated a t atmospheric pressure and ambient temperature (288-291 K). Cyclohexane was added to scavenge the hydroxyl radical which forms as a product of the ozone-unsaturated alcohol reaction. The reaction rate constants,

Kinetics and Mechanisms for the Reaction

Kinetics and Mechanisms for the Reactions of Ozone with Unsaturated Oxygenated Compounds

✍ Dr. Ismael Al Mulla; Dr. Lisa Viera; Dr. Rebecca Morris; Prof. Howard Sidebotto 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB 👁 1 views

## Abstract Rate coefficients for the reaction of ozone with a series of unsaturated oxygenated compounds are determined in air at atmospheric pressure and (298±3) K. Rate data are obtained using both relative and absolute rate techniques, and the measured rate coefficients are found to be in good

ChemInform Abstract: Rate Constants for

ChemInform Abstract: Rate Constants for the Gas-Phase Reactions of Ozone with Unsaturated Aliphatic Alcohols.

✍ E. GROSJEAN; D. GROSJEAN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB

Kinetics and mechanism of the reaction o

Kinetics and mechanism of the reaction of Ozone with Aliphatic alcohols

✍ S. Rakovski; D. Cherneva 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 415 KB 👁 1 views

## Abstract Kinetic parameters of the reaction of ozone with aliphatic alcohols of different structures are obtained. The ratio between the relative reactivities of the primary: secondary: tertiary alcohols was found to be 1:15:138. The bond energy changes in the same sense as the activation energy