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The Gas Phase Reaction of Unsaturated Oxygenates with Ozone: Carbonyl Products and Comparison with the Alkene-Ozone Reaction

โœ Scribed by Eric Grosjean; Daniel Grosjean

Book ID
110229980
Publisher
Springer Netherlands
Year
1997
Tongue
English
Weight
106 KB
Volume
27
Category
Article
ISSN
0167-7764

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๐Ÿ“œ SIMILAR VOLUMES

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reaction of ozone with unsaturated oxygenates
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 160 KB ๐Ÿ‘ 2 views

The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ฯญ 1 constants, in units of cm 3 molecule ฯช1 s ฯช1 , are for 2 (5H)-furanone, ฯช18 10 0.22 ฯฎ 0.05 for methacrolein, for crotonaldehyde, f

Carbonyl products of the gas phase react
Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Springer Netherlands ๐ŸŒ English โš– 933 KB

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p = 1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and