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The Rate Law and Mechanism for the Reaction of Cerium(IV) and Bromide Ion in Aqueous Sulfate Media 1,2

โœ Scribed by King, Edward L.; Pandow, Mary L.


Book ID
120015429
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
824 KB
Volume
75
Category
Article
ISSN
0002-7863

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The photochemical reaction of cerium(IV)
โœ E. Baciocchi; T. Del Giacco; S.M. Murgia; G.V. Sebastiani ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 884 KB

The photochemical reaction of cerium(IV) ammonium nitrate (CAN) in acetonitrile with cyclohexene, I-octene and a series of styrene derivatives leads to the formation of 1,2--dlnitrate adducts in high yields. The reaction takes place by the intermediacy of the nitrate radical which forms in the photo